You can also use a Skype button: when the visitor to the web site clicks on it, Skype initiates a call to the number.
It's as simple as that ...
Only if the the User has Skype (installed and with an account)
If the visitor does not use Skype, how can it work?
Google/Android phones come with Skype installed, but you still have to set up an account.
iPhone doesn't use Skype at all (does it?).